Effects of climate, fire and vegetation development on Holocene changes in total organic carbon concentration in three boreal forest lakes in northern Sweden

International audienceNear infrared spectroscopy (NIRS), diatoms, pollen, charcoal, loss-on-ignition (LOI), and nutrient elements in lake sediments were used to assess important factors controlling Holocene changes in the total organic carbon (TOC) concentration, pCO2, color and pH of lake water in three boreal forest lakes in northern Sweden. The results suggest that mire formation, fire frequency and humidity are the most important forcing factors on millennial timescales. Mires produce humic acids that become available to the lakes, whereas fires may reduce the pool of carbon in the catchments, and humidity controls the transportation of allochthonous carbon into the lakes. Vegetation development and temperature as sole factors are of minor importance for the TOC concentrations in these lakes on a millennial timescale. Two of the sites indicate that liming and possibly fish introduction and rotenone treatment in recent time has led to increased TOC, color and pH in the lake water, and changed the diatom community composition to an assemblage that has never been present before. Given the predicted climate change scenario that suggests a more humid climate, expanding mires and less frequent fires, our paleolimnological data suggest that TOC concentrations can be expected to increase in boreal forest lakes in the future. Since super-saturation and emission of CO2 from lakes is correlated to the TOC concentration of lake water, higher TOC concentrations may lead to increased emission of CO2 from lakes to the atmosphere

Forcing mechanisms behind variations in TOC concentration of lake waters Forcing mechanisms behind variations in total organic carbon (TOC) concentration of lake waters during the past eight centuries – palaeolimnological evidence from southern Sweden Forcing mechanisms behind variations in TOC concentration of lake waters

International audienceDecadal-scale variations in total organic carbon (TOC) concentration in lake water since AD 1200 in two small lakes in southern Sweden were reconstructed based on visible-near infrared spectroscopy (VNIRS) of their recent sediment successions. In order to assess the impacts of local land-use changes and regional variations in 5 sulphur deposition and climate on the inferred changes in TOC concentration, the same sediment records were subjected to multi-proxy palaeolimnological analyses. Changes in lake-water pH were inferred from diatom analysis, whereas pollen-based land-use reconstructions (Landscape Reconstruction Algorithm) together with geo-chemical records provided information on catchment-scale environmental changes, 10 and comparisons were made with available records of climate and population density. Our long-term reconstructions reveal that TOC concentrations were generally high prior to AD 1900, with second-order variations coupled mainly to changes in agricultural land-use intensity. The last century showed significant changes, and unusually low TOC concentrations were recorded in 1930–1990, followed by a recent increase. Vari-15 ations in sulphur emissions, with an increase in the early 1900s to a peak around AD 1980 and a subsequent decrease, were most likely the main driver of these dynamics, although processes related to the introduction of modern forestry and recent increases in precipitation and temperature may have contributed. The increase in lake-water TOC concentration from around AD 1980 may therefore reflect a recovery process. Given 20 that the effects of sulphate deposition now subside, other forcing mechanisms related to land management and climate change will possibly become the main drivers of TOC concentration changes in boreal lake waters in the future

Historical TOC concentration minima during peak sulfur deposition in two Swedish lakes

International audienceDecadal-scale variations in total organic carbon (TOC) concentration in lake water since AD 1200 in two small lakes in southern Sweden were reconstructed based on visible–near-infrared spectroscopy (VNIRS) of their recent sediment successions. In order to assess the impacts of local land-use changes, regional variations in sulfur, and nitrogen deposition and climate variations on the inferred changes in TOC concentration, the same sediment records were subjected to multi-proxy palaeolimnological analyses. Changes in lake-water pH were inferred from diatom analysis , whereas pollen-based land-use reconstructions (Landscape Reconstruction Algorithm) together with geochemical records provided information on catchment-scale environmental changes, and comparisons were made with available records of climate and population density. Our long-term reconstructions reveal that inferred lake-water TOC concentrations were generally high prior to AD 1900, with additional variability coupled mainly to changes in forest cover and agricultural land-use intensity. The last century showed significant changes, and unusually low TOC concentrations were inferred at AD 1930–1990, followed by a recent increase , largely consistent with monitoring data. Variations in sulfur emissions, with an increase in the early 1900s to a peak around AD 1980 and a subsequent decrease, were identified as an important driver of these dynamics at both sites, while processes related to the introduction of modern forestry and recent increases in precipitation and temperature may have contributed, but the effects differed between the sites. The increase in lake-water TOC concentration from around AD 1980 may therefore reflect a recovery process. Given that the effects of sulfur deposition now subside and that the recovery of lake-water TOC concentrations has reached pre-industrial levels, other forcing mechanisms related to land management and climate change may become the main drivers of TOC concentration changes in boreal lake waters in the future

Neutron diffraction study and theoretical analysis of the antiferromagnetic order and diffuse scattering in the layered Kagome system CaBaCo2_2Fe2_2O7_7

The hexagonal swedenborgite, CaBaCo$_2$Fe$_2$O$_7$, is a chiral frustrated antiferromagnet, in which magnetic ions form alternating Kagome and triangular layers. We observe a long range $\sqrt{3} \times \sqrt{3}$ antiferromagnetic order setting in below $T_N = 160$ K by neutron diffraction on single crystals of CaBaCo$_2$Fe$_2$O$_7$. Both magnetization and polarized neutron single crystal diffraction measurements show that close to $T_N$ spins lie predominantly in the $ab$-plane, while upon cooling the spin structure becomes increasingly canted due to Dzyaloshinskii-Moriya interactions. The ordered structure can be described and refined within the magnetic space group $P31m^\prime$. Diffuse scattering between the magnetic peaks reveals that the spin order is partial. Monte Carlo simulations based on a Heisenberg model with two nearest-neighbor exchange interactions show a similar diffuse scattering and coexistence of the $\sqrt{3} \times \sqrt{3}$ order with disorder. The coexistence can be explained by the freedom to vary spins without affecting the long range order, which gives rise to ground-state degeneracy. Polarization analysis of the magnetic peaks indicates the presence of long-period cycloidal spin correlations resulting from the broken inversion symmetry of the lattice, in agreement with our symmetry analysis.Comment: 12 pages, 13 figures, 2 table